Polyglyceryl-20 Hexacaprylate
AKA “Polyglyceryl-20 Ester, Emulsifier
Synthetic
Ingredient Facts
Polyglyceryl-20 hexacaprylate
AKA: Polyglyceryl-20 Ester, Emulsifier
Synthetic · Emollient · EWG: 4
Synthetic
Emollient
Cleanser
Skin Conditioner
Synthetic
Clean
1,2,3-Propanetriol homopolymer (20 mol average), hexaoctanoate Science: Functions: Surfactant - Cleansing Safety Ratings: CIR: Safe as used
CAS #
-
Form
Liquid
See origin →
Functions
Cleansing
Makes oil and water mix so dirt, makeup, and sunscreen can actually be washed away. The reason your face wash foams.
Emollient
Fills in the tiny cracks between skin cells to make everything feel smooth and soft. The "silky finish" ingredient.
Skin Conditioning
A catch-all term for ingredients that improve how skin looks and feels — softer, smoother, more supple. The workhorse behind most moisturizers.
Cleansing Surfactant
Removes Impurities
Traditional Use
Developed in the late 20th century as a synthetic emulsifier and solubilizer. Created by combining polyglycerin (derived from glycerin) with caprylic acid to improve stability and texture in modern cosmetic formulations.
Skin Types
all-skin-types
Best For
General
Melanin-Rich Skin
Suitable
Pregnancy & Breastfeeding Safe
Yes
EWG
4
CIR
Safe w/Qualifications
Pregnancy
Yes
CIR Safety Findings
Not a Sensitizer
medical-approval
all-shades-safe
Regulatory Status
USApermitted
EUrestricted
JAPANrestricted
CANADArestricted
Unexpected skin barrier influence from nonionic emulsifiers.
Bárány E, Lindberg M, Lodén M
International journal of pharmaceutics, 2000
Unexpected skin barrier influence from nonionic emulsifiers.
Bárány E, Lindberg M, Lodén M
International journal of pharmaceutics, 2000
Polyglyceryl-20 Hexacaprylate
European Commission
EU Cosmetic Ingredient Database (CosIng)
Effects of silicone emulsifiers on in vitro skin permeation of sunscreens from cosmetic emulsions.
Montenegro L, Paolino D, Puglisi G
Journal of cosmetic science, 2004
Structure and rheology of semisolid o/w creams containing cetyl alcohol/non-ionic surfactant mixed emulsifier and different polymers.
Ribeiro HM, Morais JA, Eccleston GM
International journal of cosmetic science, 2004
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
Verified Feb 2026
Data: CosIng · EWG · CIR