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Polyglyceryl-4 Caprylate
AKA “Caprylic Acid Polyglyceryl Ester, Emulsifier”
Synthetic
Ingredient Facts
Polyglyceryl-4 caprylate
AKA: Caprylic Acid Polyglyceryl Ester, Emulsifier
Synthetic · Emollient · EWG: 4
Synthetic
Emollient
Cleanser
Emulsifier
Skin Conditioner
Synthetic
Clean
Polyglyceryl-4 Caprylate is the monoester of Caprylic Acid and Polyglycerin-4 Science: Functions: Skin Conditioning - Emollient, Surfactant - Emulsifying Safety Ratings: CIR: Safe as used
CAS #
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See origin →
Functions
Emollient
Fills in the tiny cracks between skin cells to make everything feel smooth and soft. The "silky finish" ingredient.
Emulsifying
Forces oil and water to stay mixed instead of separating into layers. The unsung hero holding your lotion together.
Locks In Moisture
Traditional Use
Synthesized as a mild, plant-derived emulsifier from caprylic acid and polyglycerol. Created to provide effective emulsification in gentle cleansing products, particularly in natural and organic skincare lines.
Skin Types
●all-skin-types
Best For
General
Melanin-Rich Skin
Suitable
Pregnancy & Breastfeeding Safe
Yes
EWG
4
CIR
Safe w/Qualifications
Pregnancy
Yes
CIR Safety Findings
Not a Sensitizer
medical-approval
all-shades-safe
Regulatory Status
USA✔ permitted
EU⚠ restricted
JAPAN⚠ restricted
CANADA⚠ restricted
Unexpected skin barrier influence from nonionic emulsifiers.
Bárány E, Lindberg M, Lodén M
International journal of pharmaceutics, 2000
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Unexpected skin barrier influence from nonionic emulsifiers.
Bárány E, Lindberg M, Lodén M
International journal of pharmaceutics, 2000
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Polyglyceryl-4 Caprylate
European Commission
EU Cosmetic Ingredient Database (CosIng)
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Polyglyceryl-4 Caprylate/Caprate
European Commission
EU Cosmetic Ingredient Database (CosIng)
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Polyglyceryl-4 Caprylate
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
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Polyglyceryl-4 Caprylate/Caprate
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
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Effects of silicone emulsifiers on in vitro skin permeation of sunscreens from cosmetic emulsions.
Montenegro L, Paolino D, Puglisi G
Journal of cosmetic science, 2004
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Structure and rheology of semisolid o/w creams containing cetyl alcohol/non-ionic surfactant mixed emulsifier and different polymers.
Ribeiro HM, Morais JA, Eccleston GM
International journal of cosmetic science, 2004
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Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
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Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
→
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
→
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
→
Efficient Development of Green Emulsifier/Emollient-Based Emulsion Vehicles: From RSM Optimal Experimental Design to Abridged In Vivo Assessment.
Vukašinović M, Savić S, Cekić N, Ilić T, Pantelić I et al.
Pharmaceutics, 2023
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Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
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Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
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Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
→
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
→
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
→
Tailoring the Stability of W/O/W Liquid Foundations: A Comparative Study of Polyglycerol-Based W/O Emulsifiers.
Zhu C, Zeng L, Xie Z, Luo G, Chung LH et al.
ACS omega, 2026
→
Verified Feb 2026
Data: CosIng · EWG · CIR
Polyglyceryl-4 Caprylate — Duck Heart Ghost