4-Hydroxybenzoic Acid
AKA “p-Hydroxybenzoic acid, p-Salicylic acid, 4-Carboxyphenol, Benzoic acid, para-Hydroxybenzoic acid, p-Oxybenzoesaure
Acid
Ingredient Facts
4-hydroxybenzoic acid
AKA: P-Hydroxybenzoic acid, P-Salicylic acid, 4-Carboxyphenol, Para-Hydroxybenzoic acid, P-Oxybenzoesaure
Acid · Antioxidant · EWG: 3
Synthetic
Antioxidant
Preservative
Anti-Aging
Safety Concern
Acid
Clean
A gentle preservative that keeps formulas fresh and effective by preventing bacterial and mold growth, ensuring your product stays safe to use from first application to last.
Solubility Solubility (in 100 g of solution): 99% ethanol 38.75 g (67 °C); n-butanol 19.5 g (32.5 °C)
Formula
C7H6O3
Mol. Weight
138.12
CAS #
99-96-7
Form
Liquid
State
Pellets or Large Crystals; Dry Powder
See origin →
Functions
Preservative
Keeps your product from growing bacteria, mold, or yeast. Without these, that jar of cream becomes a petri dish in about a week.
Antimicrobial
Keeps your product from growing bacteria, mold, or yeast. Without these, that jar of cream becomes a petri dish in about a week.
Antioxidant
Fights free radicals — the unstable molecules from UV, pollution, and stress that break down collagen and cause premature aging.
Anti-Aging
Targets fine lines, wrinkles, or loss of firmness. Works by boosting collagen, speeding cell turnover, or both.
Brightening
Evens out dull skin tone for a more radiant, lit-from-within look
Anti-Inflammatory
Prevents microbial growth
Provides scent
Traditional Use
A naturally occurring compound found in various plants that was first synthesized in the 19th century. Developed as the parent compound for parabens, a class of preservatives introduced to cosmetics in the 1920s.
Skin Types
all-skin-types
Best For
General
Melanin-Rich Skin
Suitable
Pregnancy & Breastfeeding Safe
Yes
EWG
3
CIR
Safe
Pregnancy
Yes
CIR Safety Findings
Not Phototoxic
ewg-3
medical-approval
all-shades-safe
Concentration Guide
8.0%
0%11%
Reg. Limit
EU regulatory limit: 8.0%. 0,4% (as acid) for single ester 0,8% (as acid) for mixtures of esters Source: EU Cosmetics Regulation (EC) 1223/2009, Annex V (Preservatives), Entry 12. Dermal absorption: 0.1%. Source: CIR Safety Assessment (CIR Seq 746).
Regulatory Status
USApermitted
EUpermitted
JAPANpermitted
CANADApermitted
Benzyl Alcohol, Benzoic Acid, Sodium Benzoate
Cosmetic Ingredient Review (CIR) Expert Panel
International Journal of Toxicology
Final Report on the Safety Assessment of Benzyl Alcohol, Benzoic Acid, and Sodium Benzoate
Cosmetic Ingredient Review (CIR) Expert Panel
International Journal of Toxicology
Safety Assessment of Benzyl Alcohol, Benzoic Acid and its Salts, and Benzyl Benzoate
Cosmetic Ingredient Review (CIR) Expert Panel
International Journal of Toxicology
4-Hydroxybenzoic acid rescues multisystemic disease and perinatal lethality in a mouse model of mitochondrial disease.
Corral-Sarasa J, Martínez-Gálvez JM, González-García P, Wendling O, Jiménez-Sánchez L et al.
Cell reports, 2024
4-Hydroxybenzoic Acid
European Commission
EU Cosmetic Ingredient Database (CosIng)
Benzoic acid and its derivatives as naturally occurring compounds in foods and as additives: Uses, exposure, and controversy.
Del Olmo A, Calzada J, Nuñez M
Critical reviews in food science and nutrition, 2017
Benzoic acid and its derivatives as naturally occurring compounds in foods and as additives: Uses, exposure, and controversy.
Del Olmo A, Calzada J, Nuñez M
Critical reviews in food science and nutrition, 2017
Benzoic acid and its derivatives as naturally occurring compounds in foods and as additives: Uses, exposure, and controversy.
Del Olmo A, Calzada J, Nuñez M
Critical reviews in food science and nutrition, 2017
4-Hydroxybenzoic Acid
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
Benzoic Acid
Environmental Working Group (EWG)
EWG Skin Deep Cosmetics Database
Safety Assessment of Benzyl Alcohol, Benzoic Acid and its...
Wilbur Johnson, Wilma F Bergfeld, Donald V Belsito, Ronald A Hill, Curtis D Klaassen, Daniel C Liebler + 5 more
International journal of toxicology, 2017
Safety Assessment of Benzyl Alcohol, Benzoic Acid and its...
Wilbur Johnson, Wilma F Bergfeld, Donald V Belsito, Ronald A Hill, Curtis D Klaassen, Daniel C Liebler + 5 more
International journal of toxicology, 2017
Verified Feb 2026
Data: PubChem · CosIng · EWG · CIR
4-Hydroxybenzoic Acid — Duck Heart Ghost